近期，我系张亮亮副教授与化学化工系刘雅杰副教授等人合作的论文 “Efficient and low-cost Ni-NiO/Al2O3 catalysts with dual-active-sites for selective catalytic conversion of phthalic anhydride to phthalide”在《Chemical Engineering Journal》期刊发表。
论文简介如下：
A efficient and low-cost nickel-based catalyst with abundant Ni/NiO heterojunctions was constructed and applied in the hydrodeoxygenation of phthalic anhydride to phthalide. The Ni/NiO heterojunction catalysts were prepared by treating mixed metal oxides derived from NiAl-LDH with different ratio in hydrogen at 400 °C, as confirmed by the XRD, H2-TPR, TEM and XPS characterization results. The developed Ni-NiO/Al2O3(3) sample with maximal Ni/NiO heterojunction possessed significant activity in phthalic anhydride hydrogenation with 99.7 % conversion and 90.6 % selectivity of phthalide at 170 °C and 4 MPa H2, as a result the amazing activity of 15.8 mmol·g−1·s−1 was achieved. Besides, Ni-NiO/Al2O3(3) catalyst exhibited good stability in this reaction, which indicated the Ni-NiO/Al2O3(3) catalyst has wide application prospect in the hydrodeoxygenation of phthalic anhydride to phthalide. The Ni/NiO heterojunction in the catalyst was the key to achieve the amazing activity. Based on the kinetic analysis and theoretical calculations, the cooperative catalytic mechanism was found in this reaction. The design of synergetic catalyst with dual-active-sites can be achieved by partly reduced with metal oxides.
